[intro music]
Hey guys, welcome to future doctors.
My name's Stephanie and I'm going to take you behind the scenes of the research that
takes place in academic institutions, as well as the awesome graduate students behind the work
Did you know there is quite a bit of research that takes place before products, technologies,
and processes are implemented into our day to day life.
Today we are going to talk about how fundamental research actually evolves into applied research
with the production of televisions.
Companies are asking how can we make really vivid televisions with sharp images, without
wasting so much energy.
These types of questions are actually going to full under applied research.
Current LCD TV's are actually made up of a blue backlight with a layer of yellow phosphorous
over, and this combination ends up producing a white light.
This white light passes through red, green, and blue filters where the different intensities
of the light end up creating all the colors we see on our screens.
There is actually a new technology that has been developed where they replace the yellow
phosphorous layer with a new nanomaterial called quantum dots.
So instead of filtering the blue backlight, this backlight ends up becoming a source
of light for the quantum dots.
They use red and green quantum dots, so with the blue, the combination of them ends up
creating a white light.
But this white light is actually a lot purer and a lot brighter.
So we are actually to create vivid colors, and brighter colors, while using less energy.
Before this nanomaterial can be implemented, there needed to be fundamental research to
take place in order for us to understand the material before we can apply it to any type
of system.
So let's start off with asking what is a quantum dot?
Quantum dots are a semiconductor material that can partially conduct electricity.
But what makes them special?
When two or more atoms combine together, they form a molecule.
The number of energy levels depends on the number of atoms within the molecule.
On the other hand, imagine a bulk semiconductor.
This semiconductor is made up of thousands of atoms, which result in their energy levels
to appear as thick bands because there is a high density of high and low energy levels.
The number of atoms in a quantum dot are somewhere in the middle between the molecule and the
bulk semiconductor.
Their energy levels resemble the combination of the two.
The gap you see between the energy levels allows them to absorb light.
Which can then be used as current, for example as in solar panels, or they can release energy
in the form of light.
Changing the diameter of the quantum dot allows us to tune the size of the gap which then
controls the color that they emit.
As the diameter of the quantum dot decrease, the wavelength of light increases.
Because of this special property is why companies are implementing them into their televisions.
Now that we have a general understanding of what quantum dots are, the next step is to
make this material.
Alright guys, so actually in a nanoparticle synthesis lab that specializes in making quantum
dots.
The process in which we usually make this material is called SolvoThermal synthesis,
where solvent and thermal energy is an essential part of this process in order to make this
material.
I'm going to take you step by step in how we make quantum dots with first measuring
our reagents and recording them in our lab notebook.
Second is setting up apparatus in the hood, so it's in a safe environment.
Third is removing any source of oxygen or air from our system so it doesn't containment
our quantum dots.
And lastly is actually inducing our energy, which is increasing the temperature in order
to make our nanoparticles.
So the first step was to measure our reagents and record them in or lab notebook.
So we're gonna' head over to the balance to do so.
Because I have written down exactly what chemicals I'm going to be using and how much I need,
I can then start with our first step in measuring out the reagents we need for our synthesis.
There are four major reagents used in synthesizing quantum dots.
So what we first measured out was our metal salt, which is cadmium myristate.
So next is our selenium source because we're making cadmium selenide.
And at last, we need our ligand source.
So moving on the second step, we need to set up our experiment.
What we have here is a fume hood.
The fume hood allows up to have a control and safe environment to conduct our experiments,
so we're not exposing ourselves to anything harmful again.
So let's finish setting up our reaction.
And then I'm going to go ahead and start adding our reagents one-by-one.
because this is a solvothermal synthesis, we need solvent.
So now we are going to open up our reaction to vacuum.
So while this is degassing, let's take a deeper look into the science behind making nanoparticles.
Recall the three reagents we measured out earlier.
Depicted here is our metal salt, cadmium myristate.
Our anion source, selenium dioxide.
And our ligand source, which are all dissolved in our solvent.
This is the clear yellow solution we see here.
As the temperature continues to increase, the metal salt and anion source begin to dissociate
into cadmium and selenide ions.
The cadmium and selenide ions then become attracted to each other to form a monomer.
This monomer makes it more favorable to combine with ions to start forming a bigger structure
and become a quantum dot.
But in the presence of a ligand, the quantum dots remain small as the ligands prevent the
quantum dots to grow into a large crystal.
These ligands also help stabilize the quantum dots and maintain them in solution.
So as we increase the number of quantum dots in solution, we see our solution change to
an orange-red, showing a successful synthesis of the quantum dots.
We then clean our quantum dots leaving us with this clear orange-red solution.
When the right wavelength of light is absorbed, we promote the emission properties of the
quantum dots.
Here our source of light has a wavelength of 648 nanometers and our quantum dots are
emitting a wavelength of 600 nm.
As a result, we see a bright orange color!
So now that we finished synthesizing our quantum dots we need to image them in order to figure
out their size, shape, composition, and structure.
We are using a transmission electron microscope to image the quantum dots.
In contrast to optical microscopes that use white light, this uses an electron beam to
image particles in the micro to nanometer range.
So what you see here where we house the particles for imaging.
This is made up of a lacey carbon film that's held by a copper grid which holds a sample
of our quantum dots.
We place this grin into our microscope and use a special program to capture images of
our quantum dots.
Here is an image of our quantum dots.
The image provides us with information on their size and shape, where the quantum dots
we synthesized are s[herical in geometry and are around three nanometers in diameter.
the program that we use can also tell us the makeup of our quantum dots.
This spectra confirms the fact that our quantum dots are made up of cadmium and selenide.
So, what do you guys think?
We talked about how companies use applied research in order to develop a brighter, more
vivid, and more efficient television by replaced the phosphorous layer within the television
with a nanomaterial called quantum dots.
We briefly discussed about what quantum dots are and then I got to show you how they're
made by taking you to a lab at an academic institution the specialized in making nanomaterials.
Let me know what you guys want to see next time.
Would you like to tour a physics lab, would you like to tour an engineering lab, or are
you still interested in chemistry.
I hope to hear from you guys soon.
You can contact me @phuturedoctors on twitter, as well on instagram.
I'll be posting more content soon and giving you guys more information about how to can
get involved in research.
But for now I'll see you guys next time.
My name's Stephanie and this was Phuture Doctors.
[outro music]
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